4) Angelina Jolie
Photo Credit: © depositphotos
From this photo, you can tell from the passionate kissing and the award held with Angelina’s brother that this is a bizarre moment. Angelina Jolie, together with her brother, love their black outfit. Besides being popular for her bad girl unusual pranks, Angelina created an awkward moment when he suddenly kissed her brother back in 2010. However, this seemed one of her best Oscar moments.